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I worked as an electrician in a steel mill where they did hot dip galvanizing by running the steel sheet through a huge molten vat of zinc. Everyone there had mild cases of upper respiratory congestion. It was only after I left there that it went away and later read of some medical research describing the exact same thing I went through. That was almost 40 years ago. Most dangerous place I ever worked. California, just 40 miles east from San Francisco, go figure.
The compressor tank that you are using for the firebox appears to still have paint and/or primer on the exterior surfaces. That could be another source of the smoke you are experiencing. It appears that you have access to an oxyacetylene set up, use it with a rosebud to burn off that paint/primer and also burn off the zinc of any piping. Black pipe would have been a better choice, but after you burn off the zinc, that's what you'll have left.
The compressor tank that you are using for the firebox appears to still have paint and/or primer on the exterior surfaces. That could be another source of the smoke you are experiencing. It appears that you have access to an oxyacetylene set up, use it with a rosebud to burn off that paint/primer and also burn off the zinc of any piping. Black pipe would have been a better choice, but after you burn off the zinc, that's what you'll have left.